A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls

Fredrick Okumu; Mangaka Matoetoe; Olalekan Fatoki

doi:doi:10.11648/j.sjc.20130103.11

| Peer-Reviewed

A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls

Fredrick Okumu, Mangaka Matoetoe, Olalekan Fatoki

Published in Science Journal of Chemistry (Volume 1, Issue 3)

Received: 20 June 2013 Published: 10 August 2013

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Polyaniline /sawdust /titanium oxide (PANI/SD/TiO2) composite was chemically synthesised by insitu polymerization of aniline monomer in acidic medium containing sawdust and titanium oxide. The structure and morphological variations of PANI/SD/TiO2 composite were interrogated by means of spectroscopy (FTIR, UV-visible, thermal gravimetric (TG) analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Noticeable spectral and morphological changes were observed compared to pristine PANI thus, strongly suggesting chemical interaction between compounds present in the composite. Batch experiments were adopted in examining the adsorption kinetics and isotherm of selected polychlorinated biphenyl (PCB) congeners (PCB: 28, 52 and 101). Results indicate that PANI/SD/TiO2 can be used as a novel, effective and low-cost adsorbent material for lower Chlorinated PCB remediation (PCB 28). Adsorption equilibrium studies followed Freundlich for PCB 52 and Langmuir models for PCB 28 and 101. While the adsorption kinetics were best described by pseudo-second-order (PCB 28 and PCB 52) and intraparticle diffusion models (PCB 101).

Published in	Science Journal of Chemistry (Volume 1, Issue 3)
DOI	10.11648/j.sjc.20130103.11
Page(s)	29-37
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Polychlorinated biphenyl, Polyaniline, Sawdust, Adsorption, Kinetics

References

[1]	J.L. Sotelo, G. Ovejero, J.A. Delgado, I. Martinez. Water Res. 36 (2002) 599-608
[2]	H. Nollet, M. Roels, P. Lutgen, P. Van der Meeren, W. Verstraete. Chemosphere. 53 (2003) 655-665
[3]	C.G. Wu, C. DeGroot, H.O. Marcy, J.L. Schindler, C.R. Kannewurf, Y.J. Liu, W. Hirpo, M.G. Kanatzidis. Chem. Mater. 8 (1996) 1992-2004
[4]	X. Qu, M. Tian, B. Liao, A. Chen. Electrochim. Acta. 55 (2010) 5367-5374
[5]	S.H. Lin, R.S. Juang.. J. Environ. Manage. 90 (2009) 1336-1349
[6]	M. Sahin, H. Gorcay, E. Kir, Y. Sahin. Funct. Polym., 69 (2009) 673-680
[7]	R. Kunin. Pure & Appl. Chem. 46 (1976) 205-211
[8]	A.M. Li, Q.X. Zhang, G.C. Zhang, J.L. Chen, Z.H. Fei, F.Q. Liu. Chemosphere. 47 (9) (2002) 981-989
[9]	B.J. Pan, B.C. Pan, W.M. Zhang, Q.X. Zhang, S.R. Zhang, S.R. Zheng, J. Hazard. Mater. 157 (2008) 293-299
[10]	J. Huang, C. Yan, K. Huang.J. Colloid Interface Sci., 332 (1) (2009) 60-64
[11]	B.L. He, W.Q. Huang. Shanghai Scientific and Technical Education, Shanghai, (1995) 439-452
[12]	S. Meada , S.P.Armes. Synth. Met. 73 (1995) 151
[13]	A-N. Chowdhury ,M.A Yousuf , M.M. Rahman. Indian J. Chem., 41A (2002) 1562
[14]	A.B Smith, C.J Knowles. J. Biotechnol. Appl. Biochem. 12(1990) 661
[15]	B.Miksa , S. Slomkowski. Colloid Polym. Sci.273 (1995) 47.
[16]	A.N. Chowdhury, S. R. Jesmeen and M. M. Hossain. Polym. Adv. Technol. 15(2004) 633–638
[17]	M. M. Ayad and A. A. El-Nas. J. Phys. Chem 114 (2010), 14377–1438
[18]	P.A. Kumar, S. Chakraborty and M. Ray. Chem. Eng. J. 141 (2008) 130–140
[19]	D.S. Minehan, K.A Marx , S.K Tripathy . Macromolecules 27(1994) 777
[20]	B. Saoudi, N. Jammul, M.M. Chehimi, G.P. McCarthy, S.P.Armes. J. Colloid Interface Sci. 192(1997) 269
[21]	B. Saoudi, N. Jammul, M-L. Abel, M.M. Chehimi, G. Dodin. Synth. Met. 87(1997) 97
[22]	R. Ansari, F. Raofie. CODEN ECJHAO E-J., of Chem., 3 (10) (2006a) 49-59
[23]	R. Ansari, F. Raofie, CODEN ECJHAO E-J. of Chem., 3 (10) (2006b) 35-43
[24]	R. Ansari, N. K. Fahim, A. F. Delavar, The Open Process Chem. J., 2 (2009) 1-5
[25]	R. Ansari, Z. Mosayebzadeh, Iran. Polym. J. 19 (7) (2010) 541-551
[26]	H.J. Walther, J. Kaeding, P. Fecimer, Acta. Hydrochim. Hydrobiol. 12 (2) (1984) 173-181
[27]	M. Dore, P. Simon, A. Deguin, J. Victor, Water Res. 20(2) (1986) 221-232
[28]	M. Barletta, A. Gisario, G. Rubino, V. Tagliaferri, Tech. 201 (2006) 3212-3228
[29]	T.T. Waryo, E.A. Songa, M.C. Matoetoe, R.F. Ngece, P.M. Ndangili, A. AlAhmed, N.M. Jahed, P.G.L. Baker, E.I. Iwuoha. Chapter 2, Nanostructured Materials for Electrochemical Biosensors, New York: Nova Science Publishers (2009)
[30]	Q.M. Pham, D.H. Pham, J.S. Kim, E.J. Kim, S. Kim. Synth. Met. 159 (19-20) (2009) 2141-2146
[31]	S. Quillard, G. Louarn, S. Lefrant and A.G. MacDiarmid.Phys. Rev. B50 (17) (1994) 12496-12508
[32]	A.G. MacDiarmid, J.C. Chiang, M. Halpern, W.S. Huang, S.L. Mu, N.L.D. Somasiri, W.Q. Wu and S.I. Yaniger, Mol. Cryst. Liq. Cryst. 121 (1985) 173-180
[33]	P.S. Khiew, N.M. Huang, S. Radiman and M.S. Ahmad. Mater. Lett. 58 (2004) 516-521
[34]	D.W. Hatchett, M. Josowicz and J. Janata. J. Phys. Chem. B103 (1999) 10992-10998
[35]	M.G. Han, S.K. Cho, S.G. Oh and S.S. Im. Synth. Met. 126(1) (2002) 53-60
[36]	M. Trchová and J. Stejskal. Pure Appl. Chem., Vol. 83 (10) (2011) 1803–1817
[37]	M.K. Ram, O. Yavuz, V. Lahsangah and M. Aldissi. Sens. Actuators. B106 (2005) 750-757.
[38]	Y. Xia, M. Wiesinger and A.G. MacDiarmid. Chem. Mater. 7(3) (1995) 443-445
[39]	J. Stejskal, D. Hlavata, P. Holler, M. Trchova, J. Prokes and I. Sapurina. Polym. Int. 53 (2004) 294-300
[40]	P. Rannou, A. Gawlicka, D. Berner, A. Pron, M. Nechtschein and D. Djurado, Macromolecules. 31(9) (1998) 3007-3015
[41]	D. Chao, J. Chen, X. Lu, L. Liang Chen, W. Zhang, and Y. Wei. Synth. Met. 150 (2005) 47-51.
[42]	H. Zengin and G. Kalayci. Mater. Chem. Phys. 120 (2010) 46-53
[43]	M.A. Salem, A.F. Al-Ghonemiy and A.B. Zaki. Appl. Catal. B: Environ. 91 (2009) 59-66
[44]	C. Wei, Y. Zhu, X. Yang and C. Li. Mater. Sci. Eng. B: Solid-State Mater. Adv. Technol. 137(1-3) (2007) 213-216.
[45]	M.C. Gupta and S.S. Umare, Studies on poly (omethoxyaniline). Macromolecules. 25 (1992) 138-142
[46]	S. Wang, Z. Tan, Y. Li, L. Sun and T. Zhang. Thermochim. Acta. 441 (2006) 191-194
[47]	M. Ghorbani and H. Eisazadeh. Synth. Met. 162 (2002) 527-530
[48]	W. Pan, S.L. Yang, G. Li and J.M. Jiang. Eur. Polym. J. 41 (2005) 2127-2133
[49]	W. Feng, E. Sun, A. Fujii, H. Wu, K. Niihara and K. Yoshinno. Bull. Chem. Soc. Jpn. 73 (2000) 2627-2633
[50]	Z. Zhang, Z. Wei and M. Wan,. Macromolecules. 35 (15) (2002) 5937-5942
[51]	M. Pirbazari, W.J. Weber. Chemistry Water Reuse, vol. 2. Cooper N.J. (ed.) USA: Ann Arbor Science, (1981) 309-339
[52]	M.E. Uhle, Y.P. Chin, G.R. Aiken. Environ. Sci. Technol. 33 (1999) 2715-2718.
[53]	G. Bia, C.P. De Pauli, L. Borgnino. J. Environ. Manage. 100 (2012) 1-9
[54]	M.A. Abdullah, L. Chiang, M. Nadeem. Chem. Eng. J. 146 (2009) 370-376
[55]	S.L.C. Ferreira, H.M.C. Andrade, H.C. dos Santos. J. Colloid Interface Sci. 270 (2004) 276-280
[56]	T.H. Yoon, K. Benzerara, S. Ahn, R.G. Luthy, T. Tyliszczak, G.E. Brown. Environ. Sci. Technol. 40 (19) (2006) 54
[57]	M.T.O. Jonker, A.A. Koelmans. Environ. Sci. Technol. 36 (2002) 3725-3734.
[58]	G. Cornelissen, O. Gustafsson. Environ. Sci. Technol. 38 (1) (2004) 148-155. 923-5929
[59]	H. Nollet, M. Roels, P. Lutgen, P. Van der Meeren, W. Verstraete. Chemosphere. 53 (2003) 655–665

Cite This Article

Plain Text BibTeX RIS

APA Style

Fredrick Okumu, Mangaka Matoetoe, Olalekan Fatoki. (2013). A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Science Journal of Chemistry, 1(3), 29-37. https://doi.org/10.11648/j.sjc.20130103.11

Copy | Download

ACS Style

Fredrick Okumu; Mangaka Matoetoe; Olalekan Fatoki. A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Sci. J. Chem. 2013, 1(3), 29-37. doi: 10.11648/j.sjc.20130103.11

Copy | Download

AMA Style

Fredrick Okumu, Mangaka Matoetoe, Olalekan Fatoki. A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Sci J Chem. 2013;1(3):29-37. doi: 10.11648/j.sjc.20130103.11

Copy | Download

@article{10.11648/j.sjc.20130103.11,
  author = {Fredrick Okumu and Mangaka Matoetoe and Olalekan Fatoki},
  title = {A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {3},
  pages = {29-37},
  doi = {10.11648/j.sjc.20130103.11},
  url = {https://doi.org/10.11648/j.sjc.20130103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130103.11},
  abstract = {Polyaniline /sawdust /titanium oxide (PANI/SD/TiO2) composite was chemically synthesised by insitu polymerization of aniline monomer in acidic medium containing sawdust and titanium oxide. The structure and morphological variations of PANI/SD/TiO2 composite were interrogated by means of spectroscopy (FTIR, UV-visible, thermal gravimetric (TG) analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Noticeable spectral and morphological changes were observed compared to pristine PANI thus, strongly suggesting chemical interaction between compounds present in the composite. Batch experiments were adopted in examining the adsorption kinetics and isotherm of selected polychlorinated biphenyl (PCB) congeners (PCB: 28, 52 and 101). Results indicate that PANI/SD/TiO2 can be used as a novel, effective and low-cost adsorbent material for lower Chlorinated PCB remediation (PCB 28). Adsorption equilibrium studies followed Freundlich for PCB 52 and Langmuir models for PCB 28 and 101. While the adsorption kinetics were best described by pseudo-second-order (PCB 28 and PCB 52) and intraparticle diffusion models (PCB 101).},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls
AU  - Fredrick Okumu
AU  - Mangaka Matoetoe
AU  - Olalekan Fatoki
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130103.11
DO  - 10.11648/j.sjc.20130103.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 29
EP  - 37
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130103.11
AB  - Polyaniline /sawdust /titanium oxide (PANI/SD/TiO2) composite was chemically synthesised by insitu polymerization of aniline monomer in acidic medium containing sawdust and titanium oxide. The structure and morphological variations of PANI/SD/TiO2 composite were interrogated by means of spectroscopy (FTIR, UV-visible, thermal gravimetric (TG) analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Noticeable spectral and morphological changes were observed compared to pristine PANI thus, strongly suggesting chemical interaction between compounds present in the composite. Batch experiments were adopted in examining the adsorption kinetics and isotherm of selected polychlorinated biphenyl (PCB) congeners (PCB: 28, 52 and 101). Results indicate that PANI/SD/TiO2 can be used as a novel, effective and low-cost adsorbent material for lower Chlorinated PCB remediation (PCB 28). Adsorption equilibrium studies followed Freundlich for PCB 52 and Langmuir models for PCB 28 and 101. While the adsorption kinetics were best described by pseudo-second-order (PCB 28 and PCB 52) and intraparticle diffusion models (PCB 101).
VL  - 1
IS  - 3
ER  -

Copy | Download

Author Information

Fredrick Okumu

Department of Chemistry, Cape Peninsula University of technology, P.O. Box 652, Cape Town 8000, South Africa
Mangaka Matoetoe

Department of Chemistry, Cape Peninsula University of technology, P.O. Box 652, Cape Town 8000, South Africa
Olalekan Fatoki

Department of Chemistry, Cape Peninsula University of technology, P.O. Box 652, Cape Town 8000, South Africa

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Fredrick Okumu, Mangaka Matoetoe, Olalekan Fatoki. (2013). A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Science Journal of Chemistry, 1(3), 29-37. https://doi.org/10.11648/j.sjc.20130103.11

Copy | Download

ACS Style

Fredrick Okumu; Mangaka Matoetoe; Olalekan Fatoki. A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Sci. J. Chem. 2013, 1(3), 29-37. doi: 10.11648/j.sjc.20130103.11

Copy | Download

AMA Style

Fredrick Okumu, Mangaka Matoetoe, Olalekan Fatoki. A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls. Sci J Chem. 2013;1(3):29-37. doi: 10.11648/j.sjc.20130103.11

Copy | Download

@article{10.11648/j.sjc.20130103.11,
  author = {Fredrick Okumu and Mangaka Matoetoe and Olalekan Fatoki},
  title = {A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {3},
  pages = {29-37},
  doi = {10.11648/j.sjc.20130103.11},
  url = {https://doi.org/10.11648/j.sjc.20130103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130103.11},
  abstract = {Polyaniline /sawdust /titanium oxide (PANI/SD/TiO2) composite was chemically synthesised by insitu polymerization of aniline monomer in acidic medium containing sawdust and titanium oxide. The structure and morphological variations of PANI/SD/TiO2 composite were interrogated by means of spectroscopy (FTIR, UV-visible, thermal gravimetric (TG) analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Noticeable spectral and morphological changes were observed compared to pristine PANI thus, strongly suggesting chemical interaction between compounds present in the composite. Batch experiments were adopted in examining the adsorption kinetics and isotherm of selected polychlorinated biphenyl (PCB) congeners (PCB: 28, 52 and 101). Results indicate that PANI/SD/TiO2 can be used as a novel, effective and low-cost adsorbent material for lower Chlorinated PCB remediation (PCB 28). Adsorption equilibrium studies followed Freundlich for PCB 52 and Langmuir models for PCB 28 and 101. While the adsorption kinetics were best described by pseudo-second-order (PCB 28 and PCB 52) and intraparticle diffusion models (PCB 101).},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - A Novel Polyaniline Titanium Oxide Sawdust Composite Adsorbent for Polychlorinated Biphenyls
AU  - Fredrick Okumu
AU  - Mangaka Matoetoe
AU  - Olalekan Fatoki
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130103.11
DO  - 10.11648/j.sjc.20130103.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 29
EP  - 37
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130103.11
AB  - Polyaniline /sawdust /titanium oxide (PANI/SD/TiO2) composite was chemically synthesised by insitu polymerization of aniline monomer in acidic medium containing sawdust and titanium oxide. The structure and morphological variations of PANI/SD/TiO2 composite were interrogated by means of spectroscopy (FTIR, UV-visible, thermal gravimetric (TG) analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Noticeable spectral and morphological changes were observed compared to pristine PANI thus, strongly suggesting chemical interaction between compounds present in the composite. Batch experiments were adopted in examining the adsorption kinetics and isotherm of selected polychlorinated biphenyl (PCB) congeners (PCB: 28, 52 and 101). Results indicate that PANI/SD/TiO2 can be used as a novel, effective and low-cost adsorbent material for lower Chlorinated PCB remediation (PCB 28). Adsorption equilibrium studies followed Freundlich for PCB 52 and Langmuir models for PCB 28 and 101. While the adsorption kinetics were best described by pseudo-second-order (PCB 28 and PCB 52) and intraparticle diffusion models (PCB 101).
VL  - 1
IS  - 3
ER  -

Copy | Download